Synthesis,Crystal Structure and Theoretical Calculation of N-p-Tolylsulfonyl-3-acetyl-indole;
N-对-甲苯磺酰-3-乙酰基-吲哚的合成、晶体结构和理论计算(英文)
A new fused polycyclic indoline compound was synthesized from aniline,with the key step of Pd(Ⅱ)-catalyzed tandem cyclization using hydroquinidine as the ligand and molecular oxygen as a green oxidant.
以芳香氨为原料,通过烯丙基化、重排、酰基化及钯催化的氧化环合反应合成了一种新的氮杂三环吲哚啉化合物,其结构经1H NMR,13C NMR,IR及HR-MS表征。